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FTIR and NMR spectra of polymeric ionic liquids – Products of reaction between hydroxycontaining amidines and carbon dioxide

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dc.contributor.author Irgibaeva, Irina
dc.contributor.author Barashkov, Nikolay
dc.contributor.author Aldongarov, Anuar
dc.contributor.author Zhapakova, Asel
dc.contributor.author Eralinov, Alibek
dc.contributor.author Sakhno, Tamara
dc.contributor.author Seralin, Aidar
dc.contributor.author Sakhno, Yuriy
dc.date.accessioned 2024-09-12T10:27:47Z
dc.date.available 2024-09-12T10:27:47Z
dc.date.issued 2023
dc.identifier.issn 2212-9839
dc.identifier.other doi.org/10.1016/j.jcou.2023.102594
dc.identifier.uri http://rep.enu.kz/handle/enu/16258
dc.description.abstract Two hydroxy-containing amidine derivatives have been synthesized by condensation of amino-alcohols such as monoethanolamine (MEA) and tris(hydroxymethyl)aminomethane (TRIS) with N,N-dimethylformamide dimethyl acetal. Their interaction with carbon dioxide, leading to the formation of polymeric ionic liquids, was studied by FTIR and NMR spectroscopy. Dilute solutions of polymeric ionic liquids are also investigated by measuring the relative viscosity during the reaction. It has been found that during interaction of MEA-based amidine with CO2 within first 60 min of reaction the intensities ratio of absorbance bands at 1644 and 1705 cm− 1 dropped from 2.84 to 1.33. The linear relationship between the time of reaction and the mentioned ratio of intensities has been established. In the similar manner the changes in the intensities ratio of absorbance bands at 1696 and 1629 cm− 1 can be used for monitoring the reaction between TRIS-based amidine and CO2. Solution of polymeric ionic liquid prepared by reaction of TRIS-based amidine with CO2 in i-propanol has been used for measuring molecular weight (Mw = 637, Mn= 349; Mw/Mn = 1.828) by gel-permeation chromatography. ru
dc.language.iso en ru
dc.publisher Journal of CO2 Utilization ru
dc.relation.ispartofseries Volume 77;
dc.subject Carbon dioxide ru
dc.subject Amidine Kinetics of reaction ru
dc.subject FTIR spectra ru
dc.subject NMR spectra ru
dc.subject Polarity ru
dc.subject Ionic liquids ru
dc.subject Gel-permeation chromatography ru
dc.title FTIR and NMR spectra of polymeric ionic liquids – Products of reaction between hydroxycontaining amidines and carbon dioxide ru
dc.type Article ru


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