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Study of the Effect of Adding Nb2O5 on Calcium Titanate-Based Ferroelectric Ceramics

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dc.contributor.author Zdorovets, Maxim V.
dc.contributor.author Moldabayeva, Gulnaz Zh.
dc.contributor.author Zhumatayeva, Inesh Z.
dc.contributor.author Borgekov, Daryn B.
dc.contributor.author Shakirzyanov, Rafael I.
dc.contributor.author Kozlovskiy, Artem L.
dc.date.accessioned 2024-09-17T11:30:10Z
dc.date.available 2024-09-17T11:30:10Z
dc.date.issued 2023
dc.identifier.citation Zdorovets, M.V.; Moldabayeva, G.Z.; Zhumatayeva, I.Z.; Borgekov, D.B.; Shakirzyanov, R.I.; Kozlovskiy, A.L. Study of the Effect of Adding Nb2O5 on Calcium Titanate-Based Ferroelectric Ceramics. ChemEngineering 2023, 7, 103. https://doi.org/10.3390/ chemengineering7060103 ru
dc.identifier.issn 2305-7084
dc.identifier.other doi.org/10.3390/chemengineering7060103
dc.identifier.uri http://rep.enu.kz/handle/enu/16513
dc.description.abstract This paper considers the effect of adding niobium oxide (Nb2O5 ) to ferroelectric ceramics based on calcium titanate (CaTiO3 ), and establishes a connection between the observed alterations in strength and dielectric properties and the variation in the Nb2O5 dopant concentration in the ceramics’ composition. The method of mechanochemical solid-phase synthesis was used as the main method for obtaining the ceramics, followed by thermal sintering under specified conditions in order to form a stable phase composition of the ceramics, and to initialize phase transformations in the composition. Based on the assessment of the phase composition of the resulting ceramics, it was determined that a growth in the Nb2O5 dopant concentration beyond 0.10 mol results in the formation of an orthorhombic-phase CaNb2O4 of the Pbcm(57) spatial system, the weight contribution of which grows. A growth in the Nb2O5 additive concentration results in the formation of two-phase ceramics, the formation of which allows for an enhancement in the mechanical strength of ceramics and resistance to external influences. During the study of the dependence of the strength properties on the dopant concentration alteration, a three-stage change in hardness and crack resistance was established, regarding both structural ordering and phase transformations. The measurement of dielectric characteristics showed the direct dependence of dielectric losses and the dielectric constant on the phase composition of ceramics. ru
dc.language.iso en ru
dc.publisher ChemEngineering ru
dc.relation.ispartofseries Volume 7;Issue 6
dc.subject ferroelectrics ru
dc.subject doping ru
dc.subject calcium titanate ru
dc.subject ceramics ru
dc.subject strength properties ru
dc.title Study of the Effect of Adding Nb2O5 on Calcium Titanate-Based Ferroelectric Ceramics ru
dc.type Article ru


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