Abstract:
The results of studies of the ionic conductivity and the conjugated chemical diffusion coefficients (CCDC) in the
nonstoichiometric LixCu1.75Se (0 ≤ x ≤ 0.25) ternary alloys are presented. It has been observed that the values of
the ionic conductivity of Cu1.75Se copper selenide decreases with lithium doping in general owing to increasing the
the activation energy. The increasing of the conjugate chemical diffusion coefficients of the cations and electron holes
was observed with increasing of lithium content, despite the decreasing of self-diffusion coefficients of the cations and
decreasing of electron mobilities. The behavior of the conjugate chemical diffusion coefficients explained by a decrease
in the degree of non-stoichiometry of the composition, leading to an increase of the internal electric field accelerating the motion of slower particles.
