Abstract:
Superionic semiconductor chalcogenides with mixed electronic-ionic conductivity have very low lattice
thermal conductivity and are excellent thermoelectrics. Doping with other elements is one of the
methods for optimizing the useful properties of a material. In this work, nanosized polycrystalline
alloys of nonstoichiometric Cu1.85S copper sulfide with a low content of potassium are studied. The
paper presents the results of X-ray phase analysis, differential thermal analysis (DTA) and electron
microscopy of differential thermal analysis of KxCu1.85S alloys. The resulting alloys are a mixture
of phases, in which the main share is djurleite - non-stoichiometric copper sulfide of the composition
Cu1.97÷1.93S , in addition, depending on the composition of the alloy, there are impurities of monoclinic
and hexagonal chalcocite Cu2S , roxbyite Cu1.81S , anilite Cu1.75S , traces of metallic copper. All alloys
contain inclusions of Cu2O copper oxide. DTA detected a superionic phase transition from an ordered low-symmetry djurleite phase to a disordered superionic hexagonal phase of copper sulfide at about 373-383 K. In addition, DTA revealed two thermal effects at about 433 K and 460 K, which are absent in binary copper sulfide. The reason for the effects may be the redistribution of impurity potassium ions in the copper sulfide lattice.
